Purpose: The purpose of this study was to investigate the mediator role of the capital business path in the relationship between hope, resiliency and self-efficacy as the three components of positive organizational behavior and job performance. Methodology: The statistical population of the research is all employees in the organizations located in Isfahan city. The sample consisted of 217 people who were randomly selected from the staff in three companies. Five Self-evaluation questionnaires were used for collecting data. Findings: The results of statistical analysis showed that three variables of hope, resilience and self-efficacy had a positive and significant effect on the job performance indirectly through capital business path. The results also showed that direct effect of hope on job performance was not significant, but direct effect of self-efficacy and resilience was positive and significant. Discussion: These findings indicated the role of the capital business path in directing the common motivational factor of three constructs of positive organizational behavior of hope, resilience and self-efficacy.