The objective of the present study was to establish and assess the psychometric properties of the scale of emotional experience towards the spouse in 2018-19. For this purpose, all the married women in the city of Isfahan were considered as the statistical population from which 300 married women were selected as the statistical sample using convenience sampling. The research instruments included the scale of emotional experience towards the spouse, extroversion and introversion subscales of NEO Personality Inventory (Costa & McCrae, 1992), and triangulation (Dehghan and Yousefi, 2019). The data were analyzed using descriptive statistics, mean and standard deviation) and inferential statistics (correlation analysis, exploratory factor analysis, and norm determination. Convergent validity and divergent validity results revealed that the subscale of negative emotional experience towards the spouse was significantly positively related to neuroticism and triangulation (convergent validity), but negatively related to extroversion (divergent validity). The subscale of positive emotional experience towards the spouse, on the other hand, had a positive relationship to extroversion (convergent validity) and a significantly negative relationship to neuroticism and triangulation (divergent validity). Exploratory factor analysis showed two basic factors called positive emotional experience towards the spouse and negative emotional experience towards the spouse. Test-retest coefficients, at a three-week interval, confirmed test-retest reliability. Thus, based on what the results revealed, this test can be used to assess the scale of emotional experience towards the spouse in the married women both in research and psychotherapy.